Pioner of Water Science & Technology

Monday, September 18, 2017

Formation of crystals on membrane surfaces

The ions start clustering and form proto-nuclei, then start ordering themselves which are regularly shaped. This is the reversible stage but the tendency of reversibility is less than the previous stage. The final stage is the irreversible growth of crystals. Formation of crystals on the membrane surface depends on the solubility products and the concentration factor.




Saturday, September 16, 2017

Antiscalants

Antiscalants
•Are used for membrane filtration to clean the membrane surface.

Effectively controls calcium sulfate, barium
sulfate, strontium sulfate and calcium fluoride.


Effectively controls silica (preferably).
Good tolerance to aluminum, iron and manganese oxides.


fig 1. Sales on the membrane surface. (image source)


Most common antiscalants ,




Thursday, September 14, 2017

Basic concepts of membrane filtration : Rejection and Fouling

Rejection: How much solutes are rejected by the membrane is defined as the solute rejection of a membrane.
Rejection coefficient of a specific salt (NaCl, MgCl, CaCO3) can be calculated using below equation
Salt rejection coefficient R;



where, Cji0 and Cji respectively, are the salt concentrations on the feed and permeate sides of the membrane

Fouling: Fouling is the precipitation of unwanted materials on the membrane, during the membrane filtration. Fouling is categorized based on the material which is available in the feed waters; i.e.

Scaling (inorganic fouling)........compounds CaCO3, MgCO3
Organic fouling..........................humic substances
Colloidal fouling........................colloids such as silica substance
Bio fouling.................................the growth of bacteria on the membrane surface.

Effects of fouling;



Wednesday, September 13, 2017

Nano filtration membranes

Basic aspects of NF
Nano filtration (NF) membrane comes under the categorization of RO membrane. RO membrane can be categorized into three groups according to their performances; i.e. salt rejection, permeate flux/permeability and operation pressure. The categorization is as below,
1. Seawater and brackish water desalination membranes operated with 0.5–5 wt% salt solutions at pressures of 10–60 bar
2. Low-pressure nanofiltration membranes operated with 200–5000 ppm salt solutions at pressures of 5–10 bar.
3. Hyperfiltration membranes used to separate solutes from organic solvent solutions.

Further, they are recognized as loose reverse osmosis, low-pressure reverse osmosis, or more commonly, nanofiltration membranes.


Sunday, April 1, 2012

Removal of iron colloid from drinking water

Charcoal from Trema orientalis shows high absorption capacity, within few minutes high concentrated iron colloid can be absorbed. 0.01g of above charcoal is more than enough for 10ppm 250ml of iron solution. 
                                                                                                                                                 





Monday, July 25, 2011

Gem Minerals from Badulla

Geological Assessment of Mineral Deposits at Wewalhinna Village 

Uva Wellassa University Region, Sri Lanka

Executive Summary

 This report presents a comprehensive geological assessment of the mineral deposit located at Wewalhinna Village, approximately 10 kilometers from Uva Wellassa University. The site represents a significant skarn-type mineralization with multiple economic mineral occurrences, including iron-rich deposits and weathered corundum formations. The property, owned by Mr. Karunarathne, offers valuable opportunities for both educational research and potential value-addition initiatives by Uva Wellassa University undergraduates

1. Introduction and Site Location
 1.1 Geographic Context 
The Wewalhinna Village mineral deposit is situated in the Uva Province of Sri Lanka, representing an important geological formation within the Highland Complex of the country’s Precambrian crystalline basement. Located approximately 10 kilometers from Uva Wellassa University, the site provides convenient access for academic research and field studies. The area lies within the central highlands geological zone, characterized by high-grade metamorphic rocks dating back to the Precambrian era (approximately 1.9 to 2.5 billion years ago). 1.2 Land Ownership and Accessibility The property is under private ownership by Mr. Karunarathne, who has maintained the land in its natural state without commercial excavation activities. This pristine condition offers exceptional opportunities for geological study and mapping. The landowner has expressed interest in collaborative research initiatives, making the site particularly valuable for educational purposes and undergraduate research projects at Uva Wellassa University




2. Geological Setting and Skarn Formation
 2.1 Skarn-Type Mineralization
 
The deposit is classified as a skarn-type mineralization, which forms through metasomatic processes when magmatic intrusions interact with carbonate-rich host rocks. Skarn deposits are characterized by the following features: 

• Contact Metamorphism: Formation occurs at the contact zone between igneous intrusions and sedimentary or metamorphic rocks, typically limestone or dolomite. 

• Metasomatic Alteration: High-temperature fluids from the igneous body cause chemical and mineralogical changes in the surrounding rocks, creating distinctive calc-silicate minerals. 

• Economic Mineral Concentration: Skarn environments commonly host valuable minerals including iron oxides, copper, tungsten, molybdenum, and corundum (aluminum oxide). 

• Characteristic Minerals: Common skarn minerals include garnet, pyroxene, epidote, and various oxide minerals, creating distinctive color patterns and textures in the rock formations.





2.2 Regional Geological Framework

 Sri Lanka’s Highland Complex, where this deposit is located, consists primarily of granulite-facies metamorphic rocks including charnockites, metapelites, quartzites, and calc-silicate granulites. The presence of skarn mineralization suggests historical magmatic activity and subsequent metamorphic recrystallization under high pressure temperature conditions. This geological setting is consistent with other known mineral occurrences in the Uva Province, including gemstone deposits and industrial mineral concentrations

3. Identified Mineral Occurrences
 3.1 Iron-Rich Deposits
 3.1.1 Initial Misidentification and Field Observations

During initial site reconnaissance, Mr. Karunarathne reported the presence of what was believed to be a coal deposit in the frontal area of his property. However, field investigation and visual examination of collected samples revealed that the dark-colored material was not coal but rather consolidated iron-rich material, specifically described as “solid sludge of iron.” This misidentification is common in areas where weathering processes create dark, coal-like appearances in iron oxide deposits

3.1.2 Composition and Formation

 The iron-rich material likely consists of various iron oxide and hydroxide minerals, potentially including: 

• Hematite (Fe₂O₃): The most common iron oxide mineral, appearing as red to steel-gray crystals, often forming through oxidation of magnetite or other iron bearing minerals. 

• Magnetite (Fe₃O₄): A strongly magnetic iron oxide commonly found in skarn deposits, appearing as black octahedral crystals.
 
• Limonite (FeO(OH)·nH₂O): A mixture of hydrated iron oxide minerals resulting from weathering, typically appearing as yellow-brown to dark brown earthy masses. 

• Goethite (α-FeO(OH)): A common weathering product of iron-bearing minerals, contributing to the brownish coloration in weathered zones. The “solid sludge” description suggests a consolidated secondary iron formation, possibly resulting from weathering and remobilization of primary iron minerals within the skarn system. Such formations can represent economically significant iron concentrations, particularly if they occur in sufficient volume and grade

3.1.3 Economic Potential 

Iron oxide deposits associated with skarn formations can have various economic applications including raw material for iron and steel production (if sufficiently high grade), pigment production (ochre and other natural iron oxide pigments), and heavy aggregate for construction applications. Detailed chemical analysis would be required to determine the exact composition and assess commercial viability. 

3.2 Corundum Deposits 
3.2.1 Occurrence and Morphology 

Corundum (Al₂O₃) was identified within the property boundaries, occurring in characteristic barrel-shaped crystals. This morphology is typical of corundum formed under specific metamorphic conditions and is commonly observed in Sri Lankan gem deposits. The barrel or cylindrical shape results from crystal growth along the c-axis during formation, with varying degrees of hexagonal symmetry visible on crystal faces. The presence of corundum in skarn environments is particularly noteworthy, as it indicates aluminum-rich metasomatic conditions during mineralization. Corundum typically forms in aluminum-rich, silica-poor environments under high-temperature metamorphic conditions (typically 600-800°C)

3.2.2 Weathering and Erosion Patterns

 Field observations indicate that the corundum crystals have undergone significant weathering and erosion. This weathering manifests as surface etching, rounding of crystal edges, and potential development of surface pitting. The weathering process affects corundum through physical and chemical mechanisms: 
• Physical Weathering: Thermal expansion and contraction, frost wedging, and mechanical erosion by water and wind gradually break down crystal surfaces and can cause fragmentation. 
• Chemical Weathering: While corundum is highly resistant to chemical weathering due to its hardness (9 on Mohs scale) and chemical stability, prolonged exposure to weathering agents can cause surface alterations and etching patterns. 
• Liberation from Host Rock: Weathering of surrounding matrix minerals (often more susceptible to alteration than corundum) leads to liberation of corundum crystals, making them available for collection as loose crystals or in alluvial concentrations

Despite weathering effects, corundum retains its essential properties and can be processed for various industrial applications. The degree of weathering should be systematically documented through detailed mineralogical examination and photographic documentation. 

3.2.3 Physical and Chemical Properties

 Corundum is characterized by the following properties: 

• Chemical Formula: Al₂O₃ (aluminum oxide) • Crystal System: Trigonal (hexagonal) • Hardness: 9 on Mohs scale (second only to diamond) 
• Specific Gravity: 3.98-4.10 g/cm³ • Melting Point: 2,050°C (3,722°F) 
• Color Variations: Pure corundum is colorless; trace elements create varieties including ruby (red, chromium-bearing) and sapphire (blue, titanium and iron bearing), as well as other colors 
• Luster: Vitreous to adamantin

4. Value Addition Opportunities and Industrial Applications 
4.1 Ceramic Industry Applications

 Corundum represents a valuable raw material for the ceramic industry, particularly in advanced technical ceramics and refractory applications. The mineral’s exceptional properties make it suitable for: • Refractory Materials: High-temperature resistant ceramics for furnace linings, kiln furniture, and crucibles. Corundum-based refractories can withstand temperatures exceeding 1,800°C, making them essential for metallurgical and glass manufacturing processes. 
• Advanced Ceramics: Technical ceramics including spark plug insulators, wear resistant components, and high-temperature sensor housings. The material’s thermal stability and electrical insulation properties are highly valued. 
• Ceramic Glazes: Corundum particles can be incorporated into ceramic glazes to enhance durability, scratch resistance, and aesthetic properties. 
• Porcelain Manufacturing: As an additive to improve mechanical strength and reduce thermal expansion in high-quality porcelain products.


4.2 Abrasive Applications

 Due to its exceptional hardness (9 on Mohs scale), corundum is extensively used in abrasive applications: • Grinding Wheels and Abrasive Papers: Crushed and graded corundum serves as the cutting agent in various grinding, polishing, and surface preparation products. 
• Sandblasting Media: Corundum particles are effective for surface cleaning, preparation, and texturing of metals, glass, and stone. 
• Polishing Compounds: Fine-grade corundum powder is used in optical polishing and precision finishing operations. 
• Lapping and Honing: For achieving precise dimensional tolerances and superior surface finishes in precision engineering applications.

4.3 Additional Industrial Uses 

• Watch Bearings and Precision Instruments: Synthetic corundum (or high-quality natural material) is used in precision bearings for watches and scientific instruments due to its wear resistance and smooth surface finish capability. 

• Optical Applications: High-purity corundum is used in optical windows, laser components, and spectroscopic equipment due to its transparency and thermal stability. 

• Electronic Substrates: Sapphire (single-crystal corundum) substrates are critical for LED manufacturing and high-power electronic devices. 

• Gemstone Market: While weathered specimens may not be suitable for gem use, systematic sorting might identify specimens suitable for cutting as ornamental stones or lower-grade gemstones



4.4 Value Addition

Strategies for Uva Wellassa University As undergraduates of Uva Wellassa University, several value-addition pathways can be pursued to transform the raw mineral resources into marketable products: 

• Material Processing and Beneficiation: Establish small-scale processing facilities to clean, sort, and grade corundum specimens by size, quality, and color. This includes development of crushing, grinding, and classification procedures to produce specific particle size distributions for different applications. 

• Quality Assessment and Characterization: Conduct detailed mineralogical analysis using techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and chemical analysis to determine exact composition, purity, and potential contamination issues. This data enhances market value and enables targeted applications. 

• Product Development: Create value-added products such as custom abrasive compounds, polishing powders, or ceramic additives tailored to specific industry requirements. Develop partnerships with local ceramic manufacturers and industrial users. 

• Research and Development: Utilize university laboratory facilities to investigate novel applications of the corundum material, potentially developing specialized products or processes that can be patented or commercialized. 

• Educational Resource Development: Create geological teaching collections, develop field study programs, and produce educational materials documenting the deposit’s characteristics. This enhances the university’s educational resources while generating revenue through organized field trips and training programs. 

• Sustainable Mining Practices: Design and implement small-scale, environmentally responsible extraction methods that minimize environmental impact while maximizing resource recovery. This serves as a demonstration project for sustainable mineral development.

5. Recommendations and Future Work

 5.1 Immediate Actions

 • Systematic Geological Mapping: Conduct detailed geological mapping of the property to delineate the extent of mineralization, identify different rock units, and document structural features. Use GPS coordinates to create accurate location maps. 

• Sample Collection and Analysis: Collect representative samples of all mineral occurrences for comprehensive laboratory analysis including chemical composition, mineralogical identification, and physical property testing. 

• Photographic Documentation: Create a comprehensive photographic record of outcrops, mineral specimens, and geological features using standardized photography protocols with scale bars and proper lighting. 

• Stakeholder Consultation: Engage with Mr. Karunarathne to establish formal research agreements and discuss potential collaboration frameworks that benefit both the landowner and the university

5.2 Medium-Term Development

 • Resource Estimation: Conduct systematic exploration including trenching, pitting, or drilling (if feasible and permitted) to estimate the volume and grade of economic minerals present. 

• Market Assessment: Research local and regional markets for corundum products, identify potential buyers, and assess price points for different product grades and specifications. 

• Processing Technology Development: Design and test appropriate beneficiation methods, considering factors such as cost-effectiveness, environmental impact, and product quality requirements. 

• Regulatory Compliance: Investigate necessary permits and licenses required for mineral exploration and potential small-scale mining activities, ensuring full compliance with Sri Lankan mining laws and environmental regulations. 5.3 Long-Term Vision 

• Establish a University-Industry Partnership: Create a collaborative model involving the university, the landowner, and potential industrial partners to develop the resource sustainably while generating revenue and providing student learning opportunities. 

• Create a Field Study Center: Develop the site as a permanent field study location for geology, mineralogy, and mining engineering education, potentially expanding to serve other universities in Sri Lanka. 

• Research Publication: Document findings in peer-reviewed scientific journals, contributing to the geological knowledge of Sri Lanka’s mineral resources and enhancing the university’s research profile. 

• Technology Transfer: Develop processing technologies and knowledge that can be transferred to small-scale miners and mineral processors throughout the region, supporting rural economic development.

6. Conclusion

 The mineral deposit at Wewalhinna Village represents a significant geological and economic opportunity for Uva Wellassa University. The presence of skarn-type mineralization with both iron-rich deposits and weathered corundum formations provides multiple avenues for research, education, and potential commercial development. The corundum occurrences, despite weathering effects, retain substantial value for ceramic industry applications and other industrial uses. The proximity to Uva Wellassa University creates unique advantages for undergraduate participation in mineral resource development, offering hands-on learning experiences in geology, mineralogy, materials science, and sustainable resource management. Through systematic investigation, careful planning, and appropriate value-addition strategies, this deposit can serve dual purposes as an educational resource and a potential revenue generator. The collaborative relationship with the landowner, Mr. Karunarathne, provides a foundation for responsible resource development that respects property rights while creating mutual benefits. With proper scientific investigation, regulatory compliance, and strategic planning, the Wewalhinna deposit can become a model for university-led mineral resource development in Sri Lanka, demonstrating how academic institutions can contribute to sustainable economic development while advancing scientific knowledge. Moving forward, the implementation of the recommended actions will enable a comprehensive understanding of the deposit’s full potential and facilitate the development of sustainable value-addition strategies that benefit all stakeholders while maintaining environmental responsibility and educational excellence